Cheats42.net

Arturo Battle Stage:
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Defeat Arturo Plateado on the final stage of episode mode.
Hitsugaya School Costume:
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Clear Arcade Mode with Toushiro Hitsugaya.
Ice Haven:
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Complete Hitsugaya's episode mode.
Ikkaku School Costume:
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Clear Arcade Mode with Madarame Ikkaku again after unlocking all characters.
Renji School Costume:
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Clear Arcade Mode with Abarai Renji.
Shihouin Yoruichi Shunpo Costume:
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Clear Arcade mode with Shihouin Yoruichi and complete the Tutorial mode.
Unlockable Characters:
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Unlockable - How to Unlock
Aizen Sousuke - Clear Arcade Mode with Ulquiorra
Arturo Plateado - Unknown; in relation to Story Mode
Grimmjow Jaggerjack - Clear Arcade Mode with Aizen Sousuke
Hinamori Momo - Unknown; in relation to Story Mode
Hisagi Shuuhei - Unknown; in relation to Story Mode
Ichimaru Gin - Clear Arcade Mode with Matsumoto Rangiku
Kuchiki Rukia - Unknown; in relation to Story Mode
Kurotsuchi Mayuri - Clear Arcade Mode with Ishida Uryuu
Kusajishi Yachiru - Clear Arcade Mode with Yumichika Ayasegawa
Kyouraku Shunsui - Clear Arcade Mode with Sado Yasutora
Madarame Ikkaku - Unknown; in relation to Story Mode
Shihouin Yoruichi - Clear Training Mode
Soi Fon - Unknown; in relation to Story Mode
Tousen Kaname - Clear Arcade Mode with Komamura Sajin
Ukitake Juushiro - Clear Arcade Mode with Kyouraku Shunsui
Ulquiorra - Clear Arcade Mode with Ichimaru Gin
Urahara Kisuke - Clear Arcade Mode with Kurotsuchi Mayuri
Yamada Hanatarou - Unknown; in relation to Story Mode
Yamamoto Genryuusai Shigekuni - Clear Arcade Mode with Ukitake Juushiro
Yumichika Ayasegawa - Clear Arcade Mode with Madarame Ikkaku
Urahara Kisuke Shinigami Costume:
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Unlock Everything.
Yumichika School Costume:
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Clear Arcade Mode with Ayasegawa Yumichika again after unlocking all characters.